An electric vehicle battery for all seasons
New electrolyte for lithium-ion batteries performs well in frigid regions
and seasons

Date:
May 18, 2023
Source:
DOE/Argonne National Laboratory
Summary:
Scientists have developed a fluorine-containing electrolyte for
lithium- ion batteries whose charging performance remains high
in frigid regions and seasons. They also determined why it is
so effective.


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FULL STORY ==========================================================================
Many owners of electric vehicles worry about how effective their battery
will be in very cold weather. Now a new battery chemistry may have solved
that problem.

In current lithium-ion batteries, the main problem lies in the liquid electrolyte. This key battery component transfers charge-carrying
particles called ions between the battery's two electrodes, causing
the battery to charge and discharge. But the liquid begins to freeze at sub-zero temperatures. This condition severely limits the effectiveness
of charging electric vehicles in cold regions and seasons.

To address that problem, a team of scientists from the U.S. Department
of Energy's (DOE) Argonne and Lawrence Berkeley national laboratories
developed a fluorine-containing electrolyte that performs well even in
sub-zero temperatures.

"Our team not only found an antifreeze electrolyte whose charging
performance does not decline at minus 4 degrees Fahrenheit, but we
also discovered, at the atomic level, what makes it so effective," said Zhengcheng "John" Zhang, a senior chemist and group leader in Argonne's Chemical Sciences and Engineering division.

This low-temperature electrolyte shows promise of working for batteries
in electric vehicles, as well as in energy storage for electric grids
and consumer electronics like computers and phones.

In today's lithium-ion batteries, the electrolyte is a mixture of a widely available salt (lithium hexafluorophosphate) and carbonate solvents such
as ethylene carbonate. The solvents dissolve the salt to form a liquid.

When a battery is charged, the liquid electrolyte shuttles lithium
ions from the cathode (a lithium-containing oxide) to the anode
(graphite). These ions migrate out of the cathode, then pass through the electrolyte on the way into the anode. While being transported through
the electrolyte, they sit at the center of clusters of four or five
solvent molecules.

During the initial few charges, these clusters strike the anode surface
and form a protective layer called the solid-electrolyte interphase. Once formed, this layer acts like a filter. It allows only the lithium ions to
pass through the layer while blocking the solvent molecules. In this way,
the anode is able to store lithium atoms in the structure of the graphite
on charge. Upon discharge, electrochemical reactions release electrons
from the lithium that generate electricity that can power vehicles.

The problem is that in cold temperatures, the electrolyte with carbonate solvents begins to freeze. As a result, it loses the ability to transport lithium ions into the anode on charge. This is because the lithium ions
are so tightly bound within the solvent clusters. Hence, these ions
require much higher energy to evacuate their clusters and penetrate the interface layer than at room temperature. For that reason, scientists
have been searching for a better solvent.

The team investigated several fluorine-containing solvents. They were
able to identify the composition that had the lowest energy barrier for releasing lithium ions from the clusters at sub-zero temperature. They
also determined at the atomic scale why that particular composition worked
so well. It depended on the position of the fluorine atoms within each
solvent molecule and their number.

In testing with laboratory cells, the team's fluorinated electrolyte
retained stable energy storage capacity for 400 charge-discharge cycles
at minus 4 F.

Even at that sub-zero temperature, the capacity was equivalent to
that of a cell with a conventional carbonate-based electrolyte at room temperature.

"Our research thus demonstrated how to tailor the atomic structure
of electrolyte solvents to design new electrolytes for sub-zero
temperatures," Zhang said.

The antifreeze electrolyte has a bonus property. It is much safer than
the carbonate-based electrolytes that are currently used, since it will
not catch fire.

"We are patenting our low-temperature and safer electrolyte and are now searching for an industrial partner to adapt it to one of their designs
for lithium-ion batteries," Zhang said.

This research appears in Advanced Energy Materials. In addition to John
Zhang, Argonne authors are Dong-Joo Yoo, Qian Liu and Minkyu Kim. Berkeley
Lab authors are Orion Cohen and Kristin Persson.

This work was funded by the DOE Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office.

* RELATED_TOPICS
o Matter_&_Energy
# Batteries # Fuel_Cells # Energy_and_Resources #
Energy_Technology # Electricity # Alternative_Fuels #
Chemistry # Nature_of_Water
* RELATED_TERMS
o Lithium o Battery_(electricity) o Fluorine o Acid o Wood o
Mass_spectrometry o Sports o Chelation

========================================================================== Story Source: Materials provided by
DOE/Argonne_National_Laboratory. Original written by Joseph
E. Harmon. Note: Content may be edited for style and length.


========================================================================== Journal Reference:
1. Dong‐Joo Yoo, Qian Liu, Orion Cohen, Minkyu Kim, Kristin A.

Persson, Zhengcheng Zhang. Rational Design of Fluorinated
Electrolytes for Low Temperature Lithium‐Ion
Batteries. Advanced Energy Materials, 2023; DOI:
10.1002/aenm.202204182 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2023/05/230518120853.htm

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